Electrolysis

(rust removal using electricity)

I know what your thinking.. You think I've gone off my nut - removing rust with electricity?! Obviously he's lost his mind... WRONG! Rusting is an electrochemical reaction between the iron in steel and oxygen in the air - they bond quite readily with each other. Here's the trick: you can use electricity to break the bond of Iron Oxide to render it back into it's component parts. Sounds neat, huh? Right now, your thinking "What's the catch?" Mebbe it readily destroys good solid metal if your not careful? WRONG! It only attacks rust, not live steel, something that can't be said of other methods , like Naval Jelly. It must use nasty chemicals then, right? WRONG! The only chemical used is plain ole' laundry soda (not soap). Although you can use the much more toxic lye in it's place, but if it's available(and it is, Check out Arm and Hammer in the clothes detergent aisle), why would you use it? Then it must use special equipment? WRONG! A plain ole' battery charger is the only piece of equipment you need, along with an electrode - I suggest using rebar.

Let's get down to business...

The Solution: The chemical solution is nothing more than laundry soda and water at a ratio of one teaspoon or so to a gallon of water. Don't bother adding more than is necessary, it doesn't work any better and it just wastes money - the electricity does the work. I recommend using Arm & Hammer laundry soda. The solution doesn't go bad, but after a while it will get real scuzzy from the accumulated detrius in it. Until it gets really skanky, you can keep reusing it, just continue to add water as needed due to evaporation.

The Container: The solution container can be anything as long as it's non conductive and large enough for solution to circulate around the object. plastic 5 gallon "joint compound" buckets from places like Home depot are cheap, good sized and can be used with a lid to cut down on evaporation when not in use. For bigger objects, things like old(non leaking) kiddy pools or even building a temporary tank using sheet plastic works too. A good idea for long, narrow objects is plastic window boxes without drain holes. The sky's the limit.

The Power Supply: To make this work, your going to need a source of DC power. There is no exact formula for figuring power requirements, but rather a bit of simply logic : The more power you supply for a given object, the faster the process works, conversely, the bigger the object the more power you need to work in the same amount of time, and finally the bigger the object for a given amount of power, the longer it will take. That said, a 10 amp battery charger is fine for something that will fit in the 5 gallon pail, if you want to do this on larger objects on a regular basis, I suggest getting one of those hi ampage(200+) chargers available from Northern Tool. They have a 200 amp model for $120 bucks. I wouldn't recommend buying it for this if your not going to be doing big stuff regularly.

The Electrode: My suggestion for the electrode is to use common rebar, with the idea of having as much surface area of the electrode in solution as the part being done. Some people are using Stainless Steel bar with the thinking that it lasts a very long time - DON'T DO IT! While it does last, it also releases Chromium into the solution, a very toxic heavy metal. God help you if the local DEP catches you dumping it. The rebar will get eaten away over time, but it's so cheap as to make it a no brainer.

The Process: It's simple - take the part, attach a wire of some sort (the bigger the better, you may want to attach multiple wires - the wires art to keep the charge leads out of the gunk) attach the lead to the wire and attach the other lead to the electrode. Polarity is important! The electrode must be hooked up to the POSITIVE(red; +) terminal and part connected to the NEGATIVE (black; -) terminal. Also make sure the electrode isn't touching the part, if it is, the rust won't go into solution. Now that you've hooked everything up, go back and double check everything, I'll wait... Done? Everything right? Good, lets continue. With everything hooked up it's time to flick the switch. Nothing much will happen. You may see fine bubbles coming off the part. Don't worry if you don't. The only way to tell for sure if it's working is to check the meter on the charger. If the juice is flowin', it's working. Now comes the hard part: waiting. This process may take anywhere from an hour or so to a day or more. It all depends on how much rust, how big a part, and how much power you have. The idea is to turn the juice off, take the part out and check it every once in a while. If it looks like it needs more, do it, you can't hurt it. When the scuzz starts developing on the surface of the solution, just skim it off and continue - just make sure you either turn off the juice or use something non conductive. When it's finally done, turn off the power, take out the part, rinse off the solution in tap water and give it a light rub with steel wool if it still has stuff clinging to it. Use your own discretion when doing this. Last: protect the metal right away as now that it's been cleaned of rust at the atomic level, it will rust very quickly.

Links:

Here's a couple of links about this process -

Automotive resto using electrolysis

Using a home made tank and a DC welder to derust a trailer frame

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